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Hydrolysis and Oxidation in Vitrimers: Linking Chemical Degradation to Constitutive Behavior and Recyclability

US NSF grant open #nsf-2554138

Summary

Epoxy thermosets are widely used in engineering applications due to their superior adhesive strength, structural integrity, and chemical resistance. However, their permanently crosslinked molecular structure prevents reshaping or recycling after use, creating significant sustainability challenges. The emergence of covalently adaptable thermosets, known as vitrimers, offers a promising pathway toward recyclable thermoset materials. Yet, the same dynamic bond exchange mechanisms that enable vitrimer reprocessability also make them susceptible to long-term degradation in harsh environments. Prolo

Hydrolysis and Oxidation in Vitrimers: Lin…
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