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Quantum Dynamics Simulations of Polariton Photochemistry under the Collective Coupling Regime

US NSF grant open #nsf-2534752

Summary

Pengfei Huo of the University of Rochester is supported by an award from the Chemical Theory, Models, and Computational Methods program to explore how collective coupling between molecules and a quantized cavity radiation field influences photochemistry. Coupling molecules to an optical cavity generates new photon-matter hybrid states, known as polaritons, which feature delocalized excitations across molecules and cavity modes. These states have been shown to enable novel chemical reactivities and offer a promising strategy for controlling reactions by tuning fundamental photon properties. Suc

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