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Fundamental Studies of Shear Alignment and Crystallization of Molten Polymers

US NSF grant open #nsf-2603751

Summary

NON-TECHNICAL SUMMARY: When polymers crystallize, only about half of the material is crystalline, with amorphous material in between crystals that gets trapped and cannot crystallize. Applying a flow to the molten polymer stretches long chains and enables the polymer to nucleate many crystals rapidly, resulting in a finer scale structure with superior mechanical properties. With small enough crystals, each long polymer chain can span many crystals, with connections between crystals referred to as tie chains. Stronger flows stretch more polymer chains and create more tie chains for superio

Fundamental Studies of Shear Alignment and…
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